Study of Deoxygenation Efficiency on the Presence of Sodium Metabisulfite and Ascorbic Acid

Document Type : Research Article

Authors

Department of Civil Engineering, Khavaran Institute of Higher Education, Mashhad, Iran

Abstract

Dissolved Oxygen (DO) removal can be defined as deaeration or deoxygenation terms in which various methods are used to remove air molecules from water. In this study, sodium metabisulfite and ascorbic acid are experimentally used to deoxygenate Birjand drinking water, Iran and also they are applied for Retention Time (RT), Temperature (T), Hardness (H) and pH variations to measure deoxygenation efficiency. Regarding, findings showed that as RT increased to 100%, DO reduced to almost 60% as well as when T rose about to 10%, has approximately led to 80% reduction of DO concentration. Furthermore, ascorbic acid effects indicated that DO concentration decreased about 40% as T had increased to 10%. In addition, 20% reduction of RT has caused to 25% removal of DO. The effect of pH revealed that alkaline state worked better than acidic state to improve deoxygenation efficiency, as well.

Keywords

Main Subjects


[1] A. Moradian, J. Sawani, Remove dissolved oxygen compensated by hydrogen in the presence of a catalyst, Power Research Institute Tehran, 1999.
[2] R. Najar, S.A. Ahmadi, Alternative materials deoxygenation hydrazine in boiler feed water for steam, 1999.
[3] A. M.Gol Mohammadi, N.Ghasemi, P.Bigdeli, Carbohydrazide production as a viable alternative to hydrazine in deoxygenation of boiler feed water, National Iranian Chemical Engineering Congress Eleventh, Tehran, Tarbiat Modares University, 2005.
[4] K. Vuorilehto, A.Tamminen, S.Ylasaari, Electrochemical removal of dissolved oxygen from water, Journal of applied electrochemistry, 5 (1995) 973-977.
[5] I. Akira, Y. Kazauki, T. Masato, F. Michio, Removal of dissolved oxygen using non-porous hollow-fiber membranes, Journal of Membrane science 145 (1998) 111-117.
[6] S. H. Macklin, N. Utilities, W. E. Haas, Carbon dioxide and dissolved oxygen removal from makeup water by gas transfer membranes, GE water and process technologies, 2010.
[7] A. Gholipour, E. Alamatian, N. Foerstner, Assessing of channel roughness and temperature variations on wastewater quality parameters using numerical modeling, Journal of Applied Sciences and Environmental Management, 19(1) (2015) 117-25.
[8] V. Andriès, D. Couturier, Reduction of dissolved oxygen in water: Hydrazine and its organic substitutes, Materials performance, 39(7) (2000) 58-61.
[9] R. Lebeuf, Y. Zhu, V. Nardello-Rataj, J. P. Lallier, J. M. Aubry, Natural polyphenols as safe alternatives to hydroquinone for the organocatalyzed reduction of dioxygen dissolved in water by diethylhydroxylamine (DEHA), Green Chemistry, 14(3) (2012) 825-31.
[10] C. E. Housecroft, A. G. Sharpe, Chapter 16: the group 16 elements".Inorganic chemistry, 3rd Edition. Pearson.p.520. ISBN; 978-0-13-175553-6. 2008.
[11] M. Y. Lachapelle, G. Drouin, Inactivation Dates Of The Human And Guinea Pig Vitamin C Genes, Genetic, 139(2) (2010) 199–207.
[12] R. L Poole, inventor; Fischer & Porter Co., assignee. Dissolved oxygen probe. United States patent US 3,948,746. 1976 Apr 6.
[13] Stack Jr Vernon T, inventor; Weston Roy F Inc, assignee. Dissolved oxygen probe. United States patent US 3,372,103. 1968 Mar 5.
[14] M. J. Johnson, J. Borkowski, C. Engblom, Steam sterilizable probes for dissolved oxygen measurement. Biotechnology and Bioengineering, 6(4) (1964) 457-68.
[15] Miyake Y, inventor; Hokushin Electric Works, Ltd., assignee. Dissolved oxygen probe. United States patent US 4,259,165. 1981 Mar 31.
[16] W. N. Epstein, Analysis of Changes In Molar Relationships By Means Of Extra-Oral Anchorage (Head-Cap) In Treatment Of Malocclusion1, The Angle Orthodontist, 18(3) (1948) 63-9.
[17] A. P. Black, A. M. Buswell, F. A. Eidsness, A. L. Black, Review of the jar test, American Water Works Association Journal, 49(11) (1957) 1414-24.
[18] N. Shah Hoseyni, M. Sarafin, General Chemistry Practical Training, Tehran, Tehran University Press, 1995. (In Persian). Same manner. Article title. J. Fundam. Appl. Sci., 2016.
[19] A. G. Hashimoto, Methane from cattle waste: effects of temperature, hydraulic retention time, and influent substrate concentration on kinetic parameter (K), Biotechnology and Bioengineering, 24(9) (1982) 2039-52.
[20] A. K. Misra, P. Chandra, J. B. Shukla, Mathematical modeling and analysis of the depletion of dissolved oxygen in water bodies, Nonlinear analysis: real world applications, 7(5) (2006) 980-96.
[21] B. B. Blizanac, P. N. Ross, N. M. Markovic, Oxygen electroreduction on Ag (111): the pH effect, Electrochimica Acta, 52(6) (2007) 2264-71.
[22] R. Ketrane, B. Saidani, O. Gil, L. Leleyter, F. Baraud, Efficiency of five scale inhibitors on calcium carbonate precipitation from hard water: effect of temperature and concentration, Desalination,; 249(3) (2009) 1397-404.